Product ID:886 8804,RP X-OMAT LO FIXER AND REPLENISHER,WORKING SOLUTION
MSDS Date:06/12/2000
FSC:6525
NIIN:01-423-2149
Status Code:A
MSDS Number: CKTDR

EASTMAN KODAK COMPANY

343 STATE STREET
ROCHESTER, NY 14650
US

Emergency Phone: 716 722-5151

Info Phone: 716-722-5151/(800) 242-2424

Preparer: NOT PROVIDED

Cage: 19139

EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS

ROCHESTER, NY 14650-1115 US

Telephone: 716-722-5151/(800) 242-2424

Cage: 19139

WATER

CAS: 7732-18-5

RTECS: ZC0110000

AMMONIUM THIOSULFATE

CAS: 7783-18-8

RTECS: XN6465000

OSHA PEL NOT PROVIDED

ACGIH TLV: NOT PROVIDED

SODIUM THIOSULFATE

CAS: 7772-98-7

RTECS: XN6476000

OSHA PEL NOT PROVIDED

ACGIH TLV: NOT PROVIDED

ACETIC ACID

CAS: 64-19-7

RTECS: AF1225000

OSHA PEL 25 MG/M3;10 PPM

ACGIH TLV: 25 MG/M3;10 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

AMMONIUM BISULFITE

CAS: 10192-30-0

RTECS: WT3595000

OSHA PEL NOT PROVIDED

ACGIH TLV: NOT PROVIDED

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

SODIUM BISULFITE

CAS: 7631-90-5

RTECS: VZ2000000

OSHA PEL NOT PROVIDED

ACGIH TLV: 5 MG/M3

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:NOT PROVIDED
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: EXPECTED LOW HAZARD FOR
RECOMMENDED HANDLING. IN CONTACT WITH STRONG ACIDS OR IF HEATED,
SULFITES MAY LIBERATE SULFUR DIOXIDE GAS.SULFUR DIOXIDE GAS IS
IRRITATING TO RESPIRATORY TRACT. SO ME ASTHMATICS OR HYPERSENSITIVE
INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING. EYES: NO SPECIFIC
HAZARD KNOWN. MAY CAUSE TRANSIENT IRRITATION. SKIN: MATERIAL HAS
LOW POTENTIAL TO CAUSE ALLERGIC SKIN REACTIONS; HOWEVER, CASES OF
HUMAN SKIN SENSITIZATION REPORTED. INGESTION: MAY BE HARMFUL IF
SWALLOWED. ASTHMATICS/SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE
WHEEZING, CHEST TIGHTNESS, STOMACH UPSE T, HIVES, FAINTNESS,
WEAKNESS, DIARRHEA
Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION
(COMPONENTS PRESENT AT 0.1% OR MORE): - INTERNATIONAL AGENCY FOR
RESEARCH ON CANCER (IARC): NONE - AMERICAN CONFERENCE OF
GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH): NON E - NATIONAL
TOXICOLOGY PROGRAM (NTP): NONE - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION (OSHA): NONE
Effects of Overexposure:SULFUR DIOXIDE GAS IS IRRITATING TO RESPIRATORY
TRACT. EYES: MAY CAUSE TRANSIENT IRRITATION.
Medical Cond Aggravated by Exposure:SOME ASTHMATICS, HYPERSENSITIVE OR
SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING,
WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS,
WEAKNESS AND DIARRHEA.

First Aid:INHALATION: MOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. GET
MEDICAL ATTENTION IF SYMPTOMS OCCUR. EYES: ANY MATERIAL THAT
CONTACTS THE EYE SHOULD BE WASHED OUT IMMEDIATELY WITH WATER. GET
MEDICAL ATTENTI ON IF SYMPTOMS OCCUR. SKIN: WASH WITH SOAP AND
WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. WASH CONTAMINATED
CLOTHING BEFORE REUSE. DESTROY OR THOROUGHLY CLEAN CONTAMINATED
SHOES. INGESTION: INGES TION: DRINK 1-2 GLASSES OF WATER. SEEK
MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON.

Flash Point:NONE
Extinguishing Media:USE WATER SPRAY; CARBON DIOXIDE (CO2); DRY
CHEMICAL; ALCOHOL FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:SOLUTION CONTAINS A STRONG REDUCING
AGENT. DRIED PRODUCT RESIDUE CAN ACT AS A REDUCING AGENT.

Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER.
OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL,
THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
Neutralizing Agent:NOT PROVIDED

Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED TO
PREVENT THE LOSS OF WATER. KEEP AWAY FROM INCOMPATIBLE SUBSTANCES
(SEE INCOMPATIBILITY SECTION). KEEP FROM CONTACT WITH OXIDIZING
MATERIALS, HIGHLY OXYGENATED OR HALOG ENATED SOLVENTS, ORGANIC
COMPOUNDS CONTAINING REDUCIBLE FUNCTIONAL GROUPS.
Other Precautions:AVOID BREATHING MIST OR VAPOR. AVOID CONTACT WITH
EYES AND PROLONGED OR REPEATED CONTACT WITH SKIN. USE WITH ADEQUATE
VENTILATION. WASH THOROUGHLY AFTER HANDLING.

Respiratory Protection:NONE SHOULD BE NEEDED. A RESPIRATOR SHOULD BE
WORN IF HAZARDOUS DECOMPOSITION PRODUCTS ARE LIKELY TO BE OR HAVE
BEEN RELEASED. RESPIRATOR TYPE: ACID GAS. SEE STABILITY AND
REACTIVITY SECTION. IF RESP IRATORS ARE USED, A PROGRAM SHOULD BE
INSTITUTED TO ASSURE COMPLIANCE WITH OSHA STANDARD 29 CFR 1910.134.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER
HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO
CONDITIONS.
Protective Gloves:FOR PROLONGED OR REPEATED SKIN CONTACT: WEAR
IMPERVIOUS GLOVES.
Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER
Work Hygienic Practices:IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO
MINIMIZE EYE CONTACT. IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO
MINIMIZE SKIN CONTACT.
Supplemental Safety and Health
NONE

HCC:C3
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:>100.C, 212.F
Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED
Decomp Temp:Decomp Text:NOT PROVIDED
Vapor Pres:(68F): 24 MBAR (18 MM HG)
Vapor Density:0.6
Spec Gravity:1.087
pH:4.2-4.5
Viscosity:NOT PROVIDED
Evaporation Rate & Reference:NOT PROVIDED
Solubility in Water:COMPLETE
Appearance and Odor:LIQUID, COLORLESS AND ODORLESS.
Percent Volatiles by Volume:80-85 WT
Corrosion Rate:NOT PROVIDED

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, BASES, SODIUM HYPOCHLORITE (BLEACH), STRONG OXIDIZING
AGENTS, COMBUSTIBLE MATERIAL, HALOGENATED MATERIALS.
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:AMMONIA, CHLORAMINE, NITROGEN OXIDES
(NOX), SULFUR DIOXIDE. OXIDES OF NITROGEN, OXIDES OF SULFUR.

Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE
AMOUNTS OF WATER. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNINGS E VEN AFTER CONTAINER IS EMPTIED.

Toxicological Information:INHALATION: EXPECTED LOW HAZARD FOR
RECOMMENDED HANDLING. IN CONTACT WITH STRONG ACIDS / IF HEATED,
SULFITES MAY LIBERATE SULFUR DIOXIDE GAS.SULFUR DIOXIDE GAS IS
IRRITATING TO RESPIRATORY TRACT. SOM E ASTHMATICS OR HYPERSENSITIVE
INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING. EYES: NO SPECIFIC
HAZARD KNOWN. MAY CAUSE TRANSIENT IRRITATION. SKIN: MATERIAL HAS
LOW POTENTIAL TO CAUSE ALLERGIC SKIN REACTIONS; HOWEVER, CASES OF
HUMAN SKIN SENSITIZATION REPORTED. INGESTION: MAY BE HARMFUL IF
SWALLOWED. ASTHMATICS/SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE
WHEEZING, CHEST TIGHTNESS, STOMACH UPSET , HIVES, FAINTNESS,
WEAKNESS, DIARRHEA

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:FISH LC50 MG/L: >100. DAPHNID EC50 MG/L: >100. ALGAL IC50
MG/L: >100. ORGANICS READILY DEGRADABLE (>70%): YES (7 DAYS).
POTENTIAL BIOACCUMULATION: LOG POW <1. COD (APPROXIMATE G/L): 80.
BOD5 (APPROXIM ATE G/L): 65. POTENTIAL TOXICITY WASTE TREATMENT
MICROORGANISMS EC50 (MG/L): > 100.

Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS
PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE:
(716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD TIME),
MONDAY THROUGH FRIDAY.

SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR PART
372: AMMONIUM THIOSULFATE; AMMONIUM ACE TATE; AMMONIUM BISULFITE,
AS SOURCES OF AQUEOUS AMMONIA.
Federal Regulatory Information:NOT PROVIDED
State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER: NONE. MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE.